BIT Team Has Made a Series of Important Progress in the Research of Artificial Propeller Chirality and Circular Dichroism in Twisted Meta-mo
News Source: School of Physics
Editor: News Agency of BIT
Translator: Li Xinxin, News Agency of BIT
Recently, the team of professor Li Jiafang and Yao Yugui from the School of Physics of Beijing Institute of Technology (BIT) used nano-kirigami technique to prepare a three-dimensional twisted artificial propeller chiral supramolecular structure. Based on the chiral center competition mechanism, the circular dichroism in twisted meta-molecules was realized by using the structure's curve perturbation, curve rotation and other mechanisms. The series of innovations were published in the top international journals Nano Letters (IF: 11.189) and Advanced Optical Materials (IF: 9.926).
Figure 1 The geometric design ideas of artificial supramolecules and circular dichroism in twisted meta-molecules. The intracellular and intercellular blades of artificial propeller chiral molecules form two geometric chiral centers, R and L, respectively.
In previous studies, researchers mainly used spiral geometry with a clear direction to enhance the chiral interaction between light and matter. However, in order to reverse the optical chirality response of this type of configuration, this kind of optical chirality response must be mirror-symmetrically operated, which will cause a huge change in the structure. In recent years, a unique propeller-like geometric configuration has attracted great attention in the molecular field. The optical chiral response can be reversed by slightly turning the “molecular blade”. However, the research on the chirality of this three-dimensional propeller is limited to the molecular field, and faces the challenge of preparation methods in the field of micro-nano photonics.
In order to solve this problem, the research team adopted the self-developed nano-kirigami technique [Sci. Adv. 4, eaat4436 (2018), Adv. Mater. 32, 1907077 (2020), Nat. Commun. 12, 1299 (2021)]. By introducing perturbation, the team constructed two almost identical bi-geometric chiral artificial propeller supramolecular array structures, and realized the sharp sign reversal of circular dichroism. Theoretical analysis shows that the counterintuitive reversal of circular dichroism in twisted meta-molecules is triggered by the chiral competition caused by the phase-controlled chiral electric quadrupole excitation and the surface lattice resonance amplification effect.
Figure 2 Two almost identical bi-geometric chiral propeller supramolecular arrays prepared and the observed circular dichroism in twisted meta-molecules.
The new concepts and new configurations of artificial propeller chirality proposed by research [Nano Lett. 21, 6828 (2021)] provide a new paradigm for the in-depth study of chiral optical physics, and they also provide an ideal platform for development of novel chiral materials. Doctoral student Ji Changyin is the first author of the paper, and professor Li Jiafang and professor Yao Yugui from the School of Physics of BIT are the co-corresponding authors of the paper. Professor Xu Yi from Jinan University, BIT Analysis and Testing Center, High-precision Innovation Center, etc. gave strong support and assistance to the project. This work was supported by the National Natural Science Foundation of China, the National Key R&D Program, the Guangdong Key R&D Program, and the Beijing Municipal Natural Science Foundation.
Article information (# is a common work; * is the corresponding author): Chang-Yin Ji, Shanshan Chen, Yu Han, Xing Liu, Juan Liu, Jiafang Li,* and Yugui Yao*, “Artificial Propeller Chirality and Counterintuitive Reversal of Circular Dichroism in Twisted Meta-molecules”, Nano Letters 21, 6828-6834 (2021).
Article link: https://pubs.acs.org/doi/10.1021/acs.nanolett.1c01802
Related articles: Xia Li,# Chang-Yin Ji,#,* Shanshan Chen, Yu Han, Juan Liu, and Jiafang Li*, “Phase enabled circular dichroism reversal in twisted bi-chiral propeller metamolecule arrays”, Advanced Optical Materials 2021, in press (DOI: 10.1002/adom.202101191).